Hydrogen atoms in X-irradiated acid ice scavenger effects

J. Moan, B. Bøckmann

    Research output: Contribution to journalArticle

    1 Scopus citations

    Abstract

    Electrons and hydrogen atoms are trapped in comparable yields when frozen solutions of 7 M NaClO4 containing 0.25 M H+ are exposed to X rays. From scavenging experiments in this matrix we conclude that the main fraction of the trapped hydrogen atoms have mobile and scavengable hydrogen atoms as their precursors. These mobile hydrogen atoms are probably formed when electrons react with H+ ions. However, a certain fractions (≈ 30-40%) of the trapped hydrogen atoms do not have electrons as their precursors. This fraction corresponds to a yield of about 0.2-0.3 and probably arises from the decomposition of excited water molecules.

    Original languageEnglish (US)
    Pages (from-to)486-488
    Number of pages3
    JournalChemical Physics Letters
    Volume61
    Issue number3
    DOIs
    StatePublished - Mar 1 1979

    ASJC Scopus subject areas

    • Physics and Astronomy(all)
    • Physical and Theoretical Chemistry

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