New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis

Arab K. El-Qisairi; Hanan A. Qaseer; George Katsigras; Philip Lorenzi; Unnati Trivedi; Sylvia Tracz; Amy Hartman; Jason A. Miller; Patrick M. Henry

doi:10.1021/ol0273093

New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis

Arab K. El-Qisairi
, Hanan A. Qaseer
, George Katsigras
, Philip Lorenzi
, Unnati Trivedi
, Sylvia Tracz
, Amy Hartman
, Jason A. Miller
, Patrick M. Henry

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

(Matrix presented) The oxidation of olefins by chiral monometallic and bimetallic Pd(II)-Cu(II) catalysts in bromide-containing aqueous-THF reaction mixtures produced chiral 1,2-dibromides. With α-olefins, the ee's were about 95% while most of the internal alkenes gave somewhat lower enantioselectivities (∼80%).

Original language	English (US)
Pages (from-to)	439-441
Number of pages	3
Journal	Organic Letters
Volume	5
Issue number	4
DOIs	https://doi.org/10.1021/ol0273093
State	Published - Feb 20 2003
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0273093

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title = "New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis",

abstract = "(Matrix presented) The oxidation of olefins by chiral monometallic and bimetallic Pd(II)-Cu(II) catalysts in bromide-containing aqueous-THF reaction mixtures produced chiral 1,2-dibromides. With α-olefins, the ee's were about 95\% while most of the internal alkenes gave somewhat lower enantioselectivities (∼80\%).",

author = "El-Qisairi, \{Arab K.\} and Qaseer, \{Hanan A.\} and George Katsigras and Philip Lorenzi and Unnati Trivedi and Sylvia Tracz and Amy Hartman and Miller, \{Jason A.\} and Henry, \{Patrick M.\}",

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T1 - New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis

AU - El-Qisairi, Arab K.

AU - Qaseer, Hanan A.

AU - Katsigras, George

AU - Lorenzi, Philip

AU - Trivedi, Unnati

AU - Tracz, Sylvia

AU - Hartman, Amy

AU - Miller, Jason A.

AU - Henry, Patrick M.

PY - 2003/2/20

Y1 - 2003/2/20

N2 - (Matrix presented) The oxidation of olefins by chiral monometallic and bimetallic Pd(II)-Cu(II) catalysts in bromide-containing aqueous-THF reaction mixtures produced chiral 1,2-dibromides. With α-olefins, the ee's were about 95% while most of the internal alkenes gave somewhat lower enantioselectivities (∼80%).

AB - (Matrix presented) The oxidation of olefins by chiral monometallic and bimetallic Pd(II)-Cu(II) catalysts in bromide-containing aqueous-THF reaction mixtures produced chiral 1,2-dibromides. With α-olefins, the ee's were about 95% while most of the internal alkenes gave somewhat lower enantioselectivities (∼80%).

UR - https://www.scopus.com/pages/publications/0038178336

UR - https://www.scopus.com/pages/publications/0038178336#tab=citedBy

U2 - 10.1021/ol0273093

DO - 10.1021/ol0273093

M3 - Article

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AN - SCOPUS:0038178336

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VL - 5

SP - 439

EP - 441

JO - Organic Letters

JF - Organic Letters

IS - 4

ER -

New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis

Abstract

ASJC Scopus subject areas

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