Pd-C-induced catalytic transfer hydrogenation with triethylsilane

Pijus K. Mandal; John S. McMurray

doi:10.1021/jo0706123

Pd-C-induced catalytic transfer hydrogenation with triethylsilane

Pijus K. Mandal, John S. McMurray

Experimental Therapeutics

Research output: Contribution to journal › Article › peer-review

178 Scopus citations

Abstract

(Chemical Equation Presented) In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.

Original language	English (US)
Pages (from-to)	6599-6601
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	72
Issue number	17
DOIs	https://doi.org/10.1021/jo0706123
State	Published - Aug 17 2007

ASJC Scopus subject areas

Organic Chemistry

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title = "Pd-C-induced catalytic transfer hydrogenation with triethylsilane",

abstract = "(Chemical Equation Presented) In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.",

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year = "2007",

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AU - Mandal, Pijus K.

AU - McMurray, John S.

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N2 - (Chemical Equation Presented) In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.

AB - (Chemical Equation Presented) In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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Pd-C-induced catalytic transfer hydrogenation with triethylsilane

Abstract

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