Solvent control of dimensionality in titanium aryloxide coordination polymers prepared from 4,4′-bis(hydroxyphenyl)sulfide

Caitlin F. Lim; Kaysia T. Ludford; Joseph M. Tanski

doi:10.1016/j.poly.2024.116860

Solvent control of dimensionality in titanium aryloxide coordination polymers prepared from 4,4′-bis(hydroxyphenyl)sulfide

Caitlin F. Lim, Kaysia T. Ludford, Joseph M. Tanski

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal and molecular structures of three covalent metal–organic network (CMON) materials synthesized from titanium (IV) isopropoxide and the Bisphenol-A analog 4,4′-bis(hydroxyphenyl)sulfide in three different solvents have been determined. The structures of the one-dimensional chain coordination polymer [trans-Ti(μ-O:O’-OC₆H₄SC₆H₄O)₂(C₅H₅N)₂]_n (1) obtained from pyridine and the two-dimensional sheet coordination polymer {[Ti₂(μ-O:O’-OC₆H₄SC₆H₄O)₂(μ₂O:κO’-OC₆H₄SC₆H₄O)₂(C₄H₈O)₂]∙(C₄H₈O)_y}_n (2) from tetrahydrofuran both contain octahedral titanium (IV) coordination geometries, whereas the doubly interpenetrated three-dimensional coordination network [Ti₂(μ-O:O’-OC₆H₄SC₆H₄O)₂(μ₂O:κO′-OC₆H₄SC₆H₄O)₂]_n (3) synthesized from benzene contains trigonal bipyramidal titanium (IV). Each material has been characterized by single crystal and powder X-ray diffraction, elemental analysis, and by ¹H NMR quench when it contains more than one organic component.

Original language	English (US)
Article number	116860
Journal	Polyhedron
Volume	251
DOIs	https://doi.org/10.1016/j.poly.2024.116860
State	Published - Mar 15 2024
Externally published	Yes

Keywords

Aryloxide ligands
Coordination polymers
Metal organic frameworks
Titanium(IV)
X-ray crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2024.116860

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title = "Solvent control of dimensionality in titanium aryloxide coordination polymers prepared from 4,4′-bis(hydroxyphenyl)sulfide",

abstract = "The crystal and molecular structures of three covalent metal–organic network (CMON) materials synthesized from titanium (IV) isopropoxide and the Bisphenol-A analog 4,4′-bis(hydroxyphenyl)sulfide in three different solvents have been determined. The structures of the one-dimensional chain coordination polymer [trans-Ti(μ-O:O{\textquoteright}-OC6H4SC6H4O)2(C5H5N)2]n (1) obtained from pyridine and the two-dimensional sheet coordination polymer {[Ti2(μ-O:O{\textquoteright}-OC6H4SC6H4O)2(μ2O:κO{\textquoteright}-OC6H4SC6H4O)2(C4H8O)2]∙(C4H8O)y}n (2) from tetrahydrofuran both contain octahedral titanium (IV) coordination geometries, whereas the doubly interpenetrated three-dimensional coordination network [Ti2(μ-O:O{\textquoteright}-OC6H4SC6H4O)2(μ2O:κO′-OC6H4SC6H4O)2]n (3) synthesized from benzene contains trigonal bipyramidal titanium (IV). Each material has been characterized by single crystal and powder X-ray diffraction, elemental analysis, and by 1H NMR quench when it contains more than one organic component.",

keywords = "Aryloxide ligands, Coordination polymers, Metal organic frameworks, Titanium(IV), X-ray crystal structure",

author = "Lim, {Caitlin F.} and Ludford, {Kaysia T.} and Tanski, {Joseph M.}",

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T1 - Solvent control of dimensionality in titanium aryloxide coordination polymers prepared from 4,4′-bis(hydroxyphenyl)sulfide

AU - Lim, Caitlin F.

AU - Ludford, Kaysia T.

AU - Tanski, Joseph M.

PY - 2024/3/15

Y1 - 2024/3/15

N2 - The crystal and molecular structures of three covalent metal–organic network (CMON) materials synthesized from titanium (IV) isopropoxide and the Bisphenol-A analog 4,4′-bis(hydroxyphenyl)sulfide in three different solvents have been determined. The structures of the one-dimensional chain coordination polymer [trans-Ti(μ-O:O’-OC6H4SC6H4O)2(C5H5N)2]n (1) obtained from pyridine and the two-dimensional sheet coordination polymer {[Ti2(μ-O:O’-OC6H4SC6H4O)2(μ2O:κO’-OC6H4SC6H4O)2(C4H8O)2]∙(C4H8O)y}n (2) from tetrahydrofuran both contain octahedral titanium (IV) coordination geometries, whereas the doubly interpenetrated three-dimensional coordination network [Ti2(μ-O:O’-OC6H4SC6H4O)2(μ2O:κO′-OC6H4SC6H4O)2]n (3) synthesized from benzene contains trigonal bipyramidal titanium (IV). Each material has been characterized by single crystal and powder X-ray diffraction, elemental analysis, and by 1H NMR quench when it contains more than one organic component.

AB - The crystal and molecular structures of three covalent metal–organic network (CMON) materials synthesized from titanium (IV) isopropoxide and the Bisphenol-A analog 4,4′-bis(hydroxyphenyl)sulfide in three different solvents have been determined. The structures of the one-dimensional chain coordination polymer [trans-Ti(μ-O:O’-OC6H4SC6H4O)2(C5H5N)2]n (1) obtained from pyridine and the two-dimensional sheet coordination polymer {[Ti2(μ-O:O’-OC6H4SC6H4O)2(μ2O:κO’-OC6H4SC6H4O)2(C4H8O)2]∙(C4H8O)y}n (2) from tetrahydrofuran both contain octahedral titanium (IV) coordination geometries, whereas the doubly interpenetrated three-dimensional coordination network [Ti2(μ-O:O’-OC6H4SC6H4O)2(μ2O:κO′-OC6H4SC6H4O)2]n (3) synthesized from benzene contains trigonal bipyramidal titanium (IV). Each material has been characterized by single crystal and powder X-ray diffraction, elemental analysis, and by 1H NMR quench when it contains more than one organic component.

KW - Aryloxide ligands

KW - Coordination polymers

KW - Metal organic frameworks

KW - Titanium(IV)

KW - X-ray crystal structure

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JF - Polyhedron

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Solvent control of dimensionality in titanium aryloxide coordination polymers prepared from 4,4′-bis(hydroxyphenyl)sulfide

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Keywords

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